An Early bit of iron from the trackway in the province of Drenthe, Netherlands, has become dated to 1350 bce, a day Typically taken as the Middle Bronze Age for this region. In Anatolia, Alternatively, iron was in use as early as 2000 bce. There's also occasional references to iron https://brooksvofuk.wikiexcerpt.com/3084107/5_easy_facts_about_metallurgical_processes_described
The Metallurgical Processes Diaries
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